Overcoming power efficiency limitation of white fluorescence light‐emitting diodes via multilevel‐hydrogen‐bond matrix
نویسندگان
چکیده
High power efficiency and low roll-off at practical luminance are two requirements for new-generation energy-saving lighting technologies, which still bottlenecks of thermally activated delayed fluorescence (TADF) white organic light-emitting diodes (WOLED), despite the advantages TADF materials devices in cost high sustainability. Herein, we developed a spiro phosphine oxide host named SSOXSPO, can form multiple multidirectional intermolecular hydrogen bonds (IHB). The resulted multilevel IHB network integrates long-range ordered short-range disordered alignments suppressing triplet-polaron quenching (TPQ) triplet-triplet annihilation (TTA). Electronic characteristics SSOXSPO matrix further regulated, leading to optimal exciton allocation through balancing energy charge transfer. As consequence, using as host, single-emissive-layer WOLEDs realized record performance, including ultralow operation voltage ∼4.0 V, beyond fluorescent tube (70.1 lm W−1) negligible external quantum (3%) 1000 nits indoor lighting. This work demonstrates that interplays supported by matrixes facilitate synergistic effects emitters on 100% utilization.
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ژورنال
عنوان ژورنال: Aggregate
سال: 2023
ISSN: ['2692-4560', '2766-8541']
DOI: https://doi.org/10.1002/agt2.390